| Chemical Name | Tetramethyltin |
|---|
| Synonym |
{uni_hamburg}
tetramethyl-stannane
Stannane, tetramethyl-
Tetramethylstannane
tin, tetramethyl-
Tetramethylstannane-
TETRAMETHYLTIN
tetramethyl-stannan
TETRAMETHYLTIN, 99+%
Zinntetramethyl
Tetramethylcin
四甲基錫
(CH3)4Sn
tatramethyl stannane
stannane, tetramethyl-
tetramethyl-ti
TIN TETRAMETHYL
tetramethyl stannane
Tin, tetramethyl-
Tetramethyl tin
Tetramethyltin,98%
Tetramethylzinn
tetramethylstannane
四甲錫
四甲錫
TETRAMETHYLSTANNANE
tetramethyltin
TETRAMETHYLTIN(IV) |
| CAS Number | 594-27-4 |
|---|
| PubChem Substance ID | 11661 |
|---|
| EC Number | 209-833-6 |
|---|
| Beilstein Registry Number | 4,631 |
|---|
| MDL Number | MFCD00008278 |
|---|
| Reaxys-RN | 3647887 |
|---|
| Chemical Name Translation | 四甲基錫 |
|---|
| Wiswesser Line Notation | 1-SN-1&1&1 |
|---|
| LabNetwork Molecule ID | LN02129244 |
|---|
| InChI | InChI=1S/4CH3.Sn/h4*1H3; |
|---|
GHS Symbol
| WGK Germany | 3 |
|---|
| Hazard statements | |
|---|
- H225 Highly flammable liquid and vapour 高度易燃液體和蒸氣
- H330 Fatal if inhaled 吸入致命
- H410 Verytoxictoaquaticlifewithlonglastingeffects 對水生生物毒性非常大并具有長期影響。
- H310 Fatal in contact with skin 皮膚接觸致命
- H300 Fatal if swallowed 吞食致命
|
| Personal Protective Equipment |
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| Hazard Codes |
T+,N
T+;N |
| RTECS | WH8630000 |
|---|
| Precautionary statements | |
|---|
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通風良好的地方使用。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
- P305+P351+P338
- P304+P340+P310
- P501 Dispose of contents/container to..… 處理內容物/容器.....
- P403+P233
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或醫生/醫師。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防護手套/防護服/眼睛的保護物/面部保護物。
- P264 Wash hands thoroughly after handling. 處理后要徹底洗凈雙手。
- P303+P361+P353
- P284 Wear respiratory protection.? 佩戴呼吸保護裝置。
- P240 Ground/bond container and receiving equipment. 與地面接觸/連接集裝箱和接受設備。
- P270 Do not eat, drink or smoke when using this product. 使用本產品時不要吃東西，喝水或吸煙。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆電氣/通風/照明/ .../設備。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
|
| Signal word |
Danger
Warning |
| UN Number |
UN 3384 6.1/PG 1
UN1992
3384
UN3384 |
| Risk Statements | |
|---|
- R11 Highly flammable 非常易燃
- R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮膚接觸及吞食都有劇毒
- R50/53
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮膚接觸及吞食都有毒
- R36/37/38 Irritating to eyes, respiratory system and skin 對眼睛、呼吸系統和皮膚有刺激性
|
| Safety Statements | |
|---|
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接觸后，立即用大量水沖洗并征求醫生意見；
- S27 Take off immediately all contaminated clothing 立即脫掉全部污染的衣服；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 發生事故時或感覺不適時，立即求醫（可能時出示標簽）；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮膚接觸后，立即用大量…（由生產廠家指定）沖洗；
- S60 This material and its container must be disposed of as hazardous waste 該物質及其容器必須作為危險廢物處置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免釋放到環境中，參考特別指示/安全收據說明書；
- S9 Keep container in a well-ventilated place 保持容器在通風良好的場所；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴適當的防護服、手套和眼睛/面保護；
- S20 When using do not eat or drink 使用時，不得進食，飲水；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入氣體/煙霧/蒸汽/噴霧；
- S33 Take precautionary measures against static discharges 對靜電采取預防措施；
- S57 Use appropriate containment to avoid environmental contamination 使用適當容器避免環境污染；
- S16 Keep away from sources of ignition - No smoking 遠離火源，禁止吸煙；
- S4 Keep away from living quarters 遠離生活區；
- S27/28
|
| Packing Group | I |
|---|
| Hazard Class | 6.1/3 |
|---|
| Storage condition |
2-8°C |
TYPE OF TEST : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 2550 mg/m3/10M
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation
Behavioral - convulsions or effect on seizure threshold
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
NDRC** National Defense Research Committee, Office of Scientific Research
and Development, Progress Report. Volume(issue)/page/year:
NDCrc-132,FEB1942
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Intraperitoneal
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 18 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1245,1986
| Restrict |
劇毒 |
{SA}
Beil. 4 ,IV,4307
{SA}
FT-IR 1 (2), 1143:B / FT-NMR 1 (3), 737:A
{uni_hamburg} Short: II/25C
Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms
Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.
Editor: Kuchitsu, K.
Source: Landolt-B?rnstein, New Series
Volume: II/25C
Year: 2001
Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules
ISBN: 3-540-66774-1
ISBN: 978-3-540-66774-2
Internet Resource: DOI:10.1007/b71431
RefComment: VIII, 481 pages. Hardcover
Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
{uni_hamburg} Short: III/35C4
Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds
Author: Gupta, R.R.; Platzer, N.
Editor: Gupta, R.R.; Lechner, M.D.
Source: Landolt-B?rnstein, New Series
Volume: III/35C4
Year: 2001
Keyword: Hydrogen 1; Nuclear Magnetic Resonance
ISBN: 3-540-41059-7
ISBN: 978-3-540-41059-1
Internet Resource: DOI:10.1007/b76570
RefComment: VII, 299 pages. With CD-ROM. Hardcover
Abstract: This volume provides a comprehen
